Sturgill Simpson will be featured on a special episode of Austin City Limits this weekend. ACL Presents: Americana Music Festival 2014 features lots of talent both old (Loretta Lynn, Robert Plant & Patti Griffin), new (The Milk Carton Kids, St. Paul & The Broken Bones), and in-between (Jason Isbell), but it’s going to be hard for any of them to beat Simpson’s rendition of “Life Of Sin,” the song that made a believer out of Letterman last summer. Check out Simpson’s rip-roaring performance below.

ACL Presents: Americana Music Festival 2014 airs this Saturday 11/22 on PBS. Here’s the full lineup:

Rosanne Cash – “A Feather’s Not A Bird”
Parker Millsap – “Truck Stop Gospel”
Loretta Lynn – “Coal Miner’s Daughter”
The Milk Carton Kids – “Snake Eyes”
Americana All-Star Band – “You Can’t Judge A Book”
Flaco Jimenez – “Ingrato Amor”
Jackson Browne – “The Long Way Around”
St. Paul and The Broken Bones – “Grass Is Greener”
Valerie June – “You Can’t Be Told”
Patty Griffin & Robert Plant – “Ohio”
Taj Mahal – “Statesboro Blues”
Jason Isbell – “Cover Me Up”
Sturgill Simpson – “Life Of Sin”